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The
octane rating of gasoline tells
you how much the fuel can be compressed before it spontaneously
ignites. When gas ignites by compression rather than because of
the spark from the spark plug, it causes knocking in the
engine. Knocking can damage an engine, so it is not something
you want to have happening. Lower-octane gas (like
"regular" 87-octane gasoline) can handle the least
amount of compression before igniting.
The
compression ratio of your engine determines the octane rating of
the gas you must use in the car. One way to increase the
horsepower of an engine of a given displacement is to increase
its compression ratio. So a "high-performance engine"
has a higher compression ratio and requires higher-octane fuel.
The advantage of a high compression ratio is that it gives your
engine a higher horsepower rating for a given engine weight --
that is what makes the engine "high performance." The
disadvantage is that the gasoline for your engine costs more.
The
name "octane" comes from the following fact: When you
take crude oil and "crack" it in a refinery, you end
up getting hydrocarbon chains of different lengths. These
different chain lengths can then be separated from each other
and blended to form different fuels. For example, you may have
heard of methane, propane and butane. All three of them are
hydrocarbons. Methane has just a single carbon atom. Propane has
three carbon atoms chained together. Butane has four carbon
atoms chained together. Pentane has five, hexane has six,
heptane has seven and octane has eight carbons chained
together.
It
turns out that heptane handles compression very poorly. Compress
it just a little and it ignites spontaneously. Octane handles
compression very well -- you can compress it a lot and nothing
happens. Eighty-seven-octane gasoline is gasoline that contains
87-percent octane and 13-percent heptane (or some other
combination of fuels that has the same performance of the 87/13
combination of octane/heptane). It spontaneously ignites at a
given compression level, and can only be used in engines that do
not exceed that compression ratio.
During
WWI, it was discovered that you can add a chemical called tetraethyl
lead to gasoline and significantly improve its octane
rating. Cheaper grades of gasoline could be made usable by
adding this chemical. This led to the widespread use of
"ethyl" or "leaded" gasoline. Unfortunately,
the side effects of adding lead to gasoline are:
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Lead
clogs a catalytic converter and renders it inoperable within
minutes.
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The
Earth became covered in a thin layer of lead, and lead is
toxic to many living things (including humans).
When
lead was banned, gasoline got more expensive because refineries
could not boost the octane ratings of cheaper grades any more.
Airplanes are still allowed to use leaded gasoline, and octane
ratings of 115 are commonly used in super-high-performance
piston airplane engines (jet engines burn kerosene, by the way).
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